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- For an FCC lattice, $Z = 4$.
- $M = 63.55\text{ g/mol}$.
- $a = x\text{ \AA} = x \times 10^{-8}\text{ cm}$.
- $N_A \approx 6.022 \times 10^{23}$.
Given that $x \neq 0$, compare the two quantities below.
Column A: $\dfrac{x}{|x|}$
Column B: $1$
The expression $\dfrac{x}{|x|}$ is the sign function of $x$:
- If $x > 0$: $\dfrac{x}{|x|} = \dfrac{x}{x} = 1$ โ equal to Column B
- If $x < 0$: $\dfrac{x}{|x|} = \dfrac{x}{-x} = -1$ โ less than Column B
Since $x$ can be positive or negative, and we get different results, the relationship cannot be determined from the information given.
The enthalpy change \(\Delta H\) can be measured indirectly using:
Hess's law states that enthalpy change for a reaction is independent of path, allowing calculation of ฮH by summing known reactions.
The 'Filibuster' is a procedural tactic used in the:
A filibuster is a tactic used in the US Senate to delay or block a vote on a piece of legislation.
Purchases ledger control account balance: $8,232. Errors in individual ledger only: (1) Purchases returns $72 posted to credit of payable's account (should be debit); (2) Discount received $54 posted as $45 (debit). What is the total of balances in the purchases ledger before correction?
Option D ($8,385) is correct.
Error 1: Returns $72 credited instead of debited → payable's balance overstated by $144 (wrong side = double error).
Error 2: Discount posted as $45 instead of $54 → understated by $9.
Ledger total = $8,232 + $144 + $9 = $8,385
Acute Asthma Severity Classification in Children (GINA/BTS):
| Feature | Moderate | Severe | Life-Threatening |
|---|---|---|---|
| PEFR | 50โ75% predicted | 33โ50% predicted | <33% predicted |
| SpOโ | โฅ92% | <92% | <92% |
| Speech | Sentences | Phrases | Words or silent |
| RR (child) | Increased | >30/min | Bradypnea (exhaustion) |
| Accessory muscles | Mild | Marked | Paradoxical movement |
This child: PEFR 35% (<33โ50%) + SpOโ 88% (<92%) + unable to complete sentences = Severe/Life-threatening. PEFR 35% places in severe range.
Management of severe asthma:
- High-flow Oโ to maintain SpOโ \(\geq 94\%\)
- Salbutamol (back-to-back nebulization) \(2.5{-}5\,\text{mg}\) every 20 minutes
- Ipratropium bromide \(0.25\,\text{mg}\) nebulized (add for severe)
- Systemic corticosteroids: prednisolone \(1{-}2\,\text{mg/kg}\) oral or IV hydrocortisone
- IV MgSOโ \(40\,\text{mg/kg}\) (max 2 g) in life-threatening asthma
- ICU referral if deteriorating
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