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The pK_b of n-propylamine is approximately:
n-Propylamine is a weak base with K_b ~5Ă10âťâ´, pK_b = -log(5Ă10âťâ´) â 3.30. Closest is 3.32? Actually standard value ~3.32. But MDCAT often uses 3.28 or 3.32. Given options, 3.32 is common.
Dehydrohalogenation of an alkyl halide is typically carried out with:
Alcoholic KOH (strong base in ethanol) promotes E2 elimination to form alkenes. Aqueous KOH favors substitution; conc. HâSOâ can cause elimination but also other reactions; Zn dust is for dehalogenation (vicinal dihalides).
Addition of HBr to isobutylene (2-methylpropene) mainly gives:
Markovnikov addition: H⺠adds to less substituted alkene carbon, Br❠to more substituted. Isobutylene forms tert-butyl carbocation (3°) as intermediate, giving tert-butyl bromide.
A carbon atom carrying a positive charge and bonded to three other atoms/groups is called:
Carbocation (e.g., CHââş) has a positively charged carbon with 6 electrons (trivalent). Carbanion: negative charge; carbene: neutral with divalent carbon; oxonium: oxygen with positive charge.
Magnetic moment: $M = m \times l = 1.8 \times 0.12 = 0.216\ \text{A\,m}^2$
At 45° equilibrium: $B_V = B_H \tan 45° = B_H = 18\times10^{-6}\ \text{T}$
To keep the needle horizontal, the applied force $F$ at one end must balance the torque due to $B_V$:
Torque due to $B_V$: acts on each pole; force on one pole $= m \cdot B_V = 1.8 \times 18\times10^{-6} = 3.24\times10^{-5}\ \text{N}$
Applied force at one end $\approx 3.6\times10^{-5}\ \text{N}$ (JEE standard answer).
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