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$E_{cell} = E^{0}_{cell} - 0.06 \log([H^{+}][Cl^{-}])$. Since $E^{0}_{H_{2}/H^{+}} = 0$, $E^{0}_{cell} = 0.22\text{ V}$.
$0.92 = 0.22 - 0.06 \log([H^{+}]^2)$ (assuming $[H^{+}] = [Cl^{-}]$).
$0.70 = -0.12 \log[H^{+}] = 0.12 \times pH$.
$pH = 0.70 / 0.06 \approx 11.6$.
$d = 5.03894$ and $\overline{d}$ is the decimal expression for $d$ rounded to the nearest thousandth.
Compare:
Column A: The number of decimal places where $d$ and $\overline{d}$ differ
Column B: 4
When we round $d = 5.03894$ to the nearest thousandth, we get $\overline{d} = 5.039$ (since the fourth decimal place is 9, which is $\geq 5$, we round up).
Comparing digit by digit:
- Position 1 (units): both have 5 ✓
- Position 2 (tenths): both have 0 ✓
- Position 3 (hundredths): both have 3 ✓
- Position 4 (thousandths): $d$ has 8, $\overline{d}$ has 9 ✗
- Position 5 onwards: $d$ has 94, $\overline{d}$ has nothing
The positions where they differ are the thousandths place and beyond (positions 4, 5, 6...). If we count decimal places where values differ, we get 3 places (the thousandth, ten-thousandth, and hundred-thousandth positions).
Actually, re-reading: the question asks for decimal PLACES where they differ. Since $\overline{d}$ ends at thousandths, comparing through all decimal places in $d$: they differ at the 4th and 5th decimal positions. That's 2 places, which is less than 4.
Therefore Column B is greater.
A metal oxide has the formula M$_{0.98}$O. The metal M exists as M$^{2+}$ and M$^{3+}$ ions. What fraction of the metal exists as M$^{3+}$?
Let $x$ = fraction of M as M$^{3+}$, $(0.98 - x)$ = fraction as M$^{2+}$.
Charge balance (O$^{2-}$ contributes $-2$): $2(0.98-x) + 3x = 2$
$1.96 - 2x + 3x = 2$
$x = 0.04$
Fraction of M as M$^{3+}$ $= \dfrac{0.04}{0.98} \times 100 \approx \mathbf{4.08\%}$
Bulk Modulus $K = \frac{\Delta P}{-\Delta V/V}$.
- The change in pressure is $\Delta P = \frac{mg}{a}$.
- The fractional change in volume for a sphere is $\frac{\Delta V}{V} = 3\frac{dr}{r}$.
- $K = \frac{mg/a}{3dr/r} \implies \frac{dr}{r} = \frac{mg}{3Ka}$.
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