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The Maternal Mortality Ratio (MMR) is defined as:
\\text{MMR} = \\frac{\\text{Number of maternal deaths}}{\\text{Number of live births}} \\times 100{,}000
It is expressed per 100,000 live births. This is distinct from the Maternal Mortality Rate, which uses the total female population of reproductive age as the denominator. Pakistan's MMR remains high compared to global targets, making this a key indicator for community health nursing assessment.
For adiabatic expansion: $T_1 V_1^{\gamma-1} = T_2 V_2^{\gamma-1}$
$300 \times V^{2/3} = T_2 \times (2V)^{2/3} \implies T_2 = \frac{300}{2^{2/3}} \approx \frac{300}{1.587} \approx 189 \text{ K}$
Change in internal energy: $\Delta U = n C_v \Delta T = n \left(\frac{3}{2}R\right) (T_2 - T_1)$
$\Delta U = 2 \times 1.5 \times 8.31 \times (189 - 300) \approx 24.93 \times (-111) \approx -2767 \text{ J} \approx -2.7 \text{ kJ}$.
Mn (Z=25): configuration [Ar] 3d⁵ 4s². After losing 2e⁻ → [Ar] 3d⁵ (half-filled, very stable). Removing the 3rd electron from a half-filled 3d⁵ shell requires breaking extra stability — very high energy needed.
Therefore, Mn has the highest third ionisation enthalpy among these elements.
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